Observation of a half step magnetization in the {Cu-3}-type triangular spin ring

We report pulsed field magnetization and ESR experiments on a {Cu-3} nanomagnet, where antiferromagnetically coupled Cu2+ (S=1/2) ions form a slightly distorted triangle. The remarkable feature is the observation of a half step magnetization, hysteresis loops, and an asymmetric magnetization between a positive and a negative field in a fast sweeping external field. This is attributed to an adiabatic change of magnetization. The energy levels determined by ESR unveil that the different mixing nature of a spin chirality of a total S=1/2 Kramers doublet by virtue of Dzyaloshinskii-Moriya interactions is decisive for inducing half step magnetization.</p

Magnetic characterization of the frustrated three-leg ladder compound [(CuCl2tachH)3Cl]Cl2

We report the magnetic features of a new one-dimensional stack of antiferromagnetically coupled equilateral copper(II) triangles. High-field magnetization measurements show that the interaction between the copper triangles is of the same order of magnitude as the intra-triangle exchange although only coupled via hydrogen bonds. The infinite chain turns out to be an interesting example of a frustrated cylindrical three-leg ladder with competing intra- and inter-triangle interactions. We demonstrate that the ground state is a spin singlet which is gaped from the triplet excitation.Comment: 6 pages, 9 figures, revised version submitted to Phys. Rev. B. More information at http://obelix.physik.uni-osnabrueck.de/~schnack

A table-top, repetitive pulsed magnet for nonlinear and ultrafast spectroscopy in high magnetic fields up to 30 T

We have developed a mini-coil pulsed magnet system with direct optical access, ideally suited for nonlinear and ultrafast spectroscopy studies of materials in high magnetic fields up to 30 T. The apparatus consists of a small coil in a liquid nitrogen cryostat coupled with a helium flow cryostat to provide sample temperatures down to below 10 K. Direct optical access to the sample is achieved with the use of easily interchangeable windows separated by a short distance of ~135 mm on either side of the coupled cryostats with numerical apertures of 0.20 and 0.03 for measurements employing the Faraday geometry. As a demonstration, we performed time-resolved and time-integrated photoluminescence measurements as well as transmission measurements on InGaAs quantum wells.Comment: 7 pages, 6 figure

Reply to "Comment on `Transition from Bose glass to a condensate of triplons in Tl1−x_{1-x}Kx_xCuCl3_3'"

Showing low-temperature specific heat and other experimental data and also on the basis of established physics, we argue against the comment made by Zheludev and H\"{u}vonnen criticizing our recent study on the magnetic-field-induced spin ordering and critical behavior in Tl$_{1-x}$K$_x$CuCl$_3$, which is described as the Bose glass-condensate transition of triplons.Comment: 2 pages, 2 figures, accepted for publication in Phys. Rev.

Degenerate ground state in the classical pyrochlore antiferromagnet Na3_3Mn(CO3_3)2_2Cl

In an ideal classical pyrochlore antiferromagnet without perturbations, an infinite degeneracy at a ground state leads to absence of a magnetic order and spin-glass transition. Here we present Na$_3$Mn(CO$_3$)$_2$Cl as a new candidate compound where classical spins are coupled antiferromagnetically on the pyrochlore lattice, and report its structural and magnetic properties.The temperature dependences of the magnetic susceptibility and heat capacity, and the magnetization curve are consistent with those of an $S$ = 5/2 pyrochlore lattice antiferromagnet with nearest-neighbor interactions of 2 K. Neither an apparent signature of a spin-glass transition nor a magnetic order is detected in magnetization and heat capacity measurements, or powder neutron diffraction experiments. On the other hand, an antiferromagnetic short-range order from the nearest neighbors is evidenced by the $Q$-dependence of the diffuse scattering which develops around 0.85 \AA$^{-1}$. A high degeneracy near the ground state in Na$_3$Mn(CO$_3$)$_2$Cl is supported by the magnetic entropy estimated as almost 4 J K$^{-2}$ mol$^{-1}$ at 0.5 K.Comment: 9 pages, 7 figures, accepted to PR

Determination of exchange energies in the sawtooth spin ring {Mo75V20} by ESR

The magnetism of the polyoxometalate cluster {Mo75V20}, containing a sawtooth ring of 10 corner-sharing triangles located on the equator of the barrel-shaped molecule, has remained debatable since it is masked by contributions from impurities as well as temperature-independent paramagnetism. In this article we demonstrate the usefulness of ESR measurements since the temperature dependence of the ESR intensity can discriminate between impurity and molecular contributions. We determine the exchange parameters and therefore also the low-lying spectrum of {Mo75V20}, especially the low-lying singlet states which so far have been probed solely by specific heat measurements.Comment: 5 pages, 5 figures, submitted to PR

Heat capacity uncovers physics of a frustrated spin tube

We report on refined experimental results concerning the low-temperature specific heat of the frustrated spin tube material [(CuCl2tachH)3Cl]Cl2. This substance turns out to be an unusually perfect spin tube system which allows to study the physics of quasi-one dimensional antiferromagnetic structures in rather general terms. An analysis of the specific heat data demonstrates that at low enough temperatures the system exhibits a Tomonaga-Luttinger liquid behavior corresponding to an effective spin-3/2 antiferromagnetic Heisenberg chain with short-range exchange interactions. On the other hand, at somewhat elevated temperatures the composite spin structure of the chain is revealed through a Schottky-type peak in the specific heat located around 2 K. We argue that the dominating contribution to the peak originates from gapped magnon-type excitations related to the internal degrees of freedom of the rung spins.Comment: 4+ pages, 6 figure